Rodrigo's first half strike saw Valencia beat Ajax 1-0 in their final Champions League group game, sealing top spot for the Spanish side and consigning the Dutch outfit to the Europa League.
Rodrigo Moreno scored the only goal in the first half as Albert Celades' men secured a surprise victory that means they finish top of the group, ahead of Chelsea in second spot, despite Gabriel's late red card.
Ajax reached the semi-finals last season, knocking out Real Madrid and Juventus during a thrilling run, but they were edged out by the LaLiga side at the Johan Cruijff Arena on Wednesday.
Rodrigo headed wide in the second minute but scored the decisive goal midway through the first half, taking advantage of Joel Veltman playing him onside.
Ferran Torres shaped to shoot from outside the box but instead played a clever disguised pass into the feet of Rodrigo, who fired into the roof of the net.
Jaume Domenech reacted well to keep out a cross-shot from Hakim Ziyech that looked to be curling inside the far post, then Andre Onana denied Rodrigo at the other end.
Rodrigo continued to offer Valencia's main threat and went close again in the 55th minute, and Ziyech wasted a clear chance from six yards as Ajax grew increasingly nervous.
Noa Lang's acrobatic effort flew wide before Erik ten Hag sent on Klaas Jan Huntelaar, and Domenech had to save from Lisandro Martinez and Ziyech at the death.
Gabriel then saw red for appearing to headbutt Ajax captain Dusan Tadic in added time, but the 10 men held on to qualify.
What does it mean? Europa League beckons for Ajax
Ajax started the campaign with successive 3-0 wins, putting themselves in a dominant position, but they will play in the Europa League next year despite collecting 10 points.
The sales of Frenkie de Jong and Matthijs de Ligt to Barcelona and Juventus respectively sapped the Eredivisie giants of their star power, with Valencia recovering from their 3-0 home loss in the reverse fixture to squeeze through.
JamesWalker
1645
But the Good news is UEFA EUROPAL LEAGUE just got hot & Interesting ππ₯
VanishPrasad
595
Inter Ajax ManU Arsenal Salzburg Benfica Well it seems Thursdays nights have got some big matches to deliver and Europa league must be happy with these results! π
oheneantwib
503
In the current age of football having a good season in a particular year doesn't guarantee that you will have successful one the next season. Unless your are that team, you'll know how I about to mention.
jibsonflexy
480
Ajax to trouble Arsenal and Manchester United
Rashnic/GOAT/CR7
472
From last to top, weldon Valencia
ommarri12
417
Too bad for Ajax.. you can't sell your best players and expect things to stay the same. good luck playing Europa league!!!
Ossboy
401
Tell Ajax, if you type your big Brothers "RM, Juve". One day will come, you little brothers "Valencia" will make you the same.ππππ€£π€£
Toblana
386
Juventus and Madrid fans have a party tonightπππ
RetroTee101
374
Europa will be a bit tough this Season.... Inter and Ajax just joined in and might be very hard to predict who will win Europa
JohnWick7
365
Arsenal and Man utd be like: Whats the meaning of this nonsense, Ajax, inter, Salzburg...i quit already
Kareem_10
360
Ajax is going to be just like Monaco,π€·π½ββοΈ they had a good season then the next season they sell their best players and stat to suffer
Cypher100
354
Me calculating how Ajax loss the match
Rashnic/GOAT/CR7
306
Man united fans be like: So even Europa we won't take[Crylaugh][Crylaugh][Crylaugh][Crylaugh]
PaschLil
302
4 Spanish teams in the knockout stages
Fiuaeiky
287
From last year semi finalists to this year Europa League qualifiers [Crylaugh][Crylaugh][Crylaugh]
Valon23
169
And I thought arsenal would actually win UEL but...
tonlnosu
95
they fell down during Champions league defeat last season and they are repeating same thing, i suggest they should carry bed when next time they want to play