Real Madrid defeated Valencia 3-0 away on LaLiga Matchday 12. According to statistics, José Mourinho has the highest win percentage among coaches who have managed at least 100 matches in LaLiga history.
Including this victory, José Mourinho has won 97 of his 126 matches as a manager in LaLiga, giving him a win rate of 77.0%, ahead of 2nd-ranked Pep Guardiola.
LaLiga All-Time Coaching Win Percentage Rankings (At Least 100 Matches Coached):
José Mourinho: 77.0% win rate (97 wins in 126 matches)
Pep Guardiola: 76.3% (116 wins in 152 matches)
Ancelotti: 71.1% win rate (162 wins in 228 matches)
Xavi: 69.6% (71 wins in 102 matches)
Zidane: 67.8% (124 wins in 183 matches)
Luis Enrique: 66.4% (101 wins in 152 matches)
In addition, Barcelona coach Hansi Flick has managed 87 matches in LaLiga, winning 69 for a win percentage of 79.3%. Although his win percentage is higher than Mourinho’s, he has yet to reach 100 matches in charge and is therefore not included on this list.